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1

Living ethylene/norbornene copolymerisation catalyzed by titanium complexes having two pyrrolide-imine chelate ligandsElectronic supplementary information (ESI) available: general procedures and materials, ligand and complex syntheses and analyses, polymerisation procedure, polymer analyses, 13C NMR spectra for polymers (entries 1 and 2). See http://www.rsc.org/suppdata/cc/b2/b202391a/

Yoshida, Yasunori, Saito, Junji, Mitani, Makoto, Takagi, Yukihiro, Matsui, Shigekazu, Ishii, Sei-ichi, Nakano, Takashi, Kashiwa, Norio, Fujita, Terunori

Journal:

Chemical Communications

Année:

2002

Langue:

english

Fichier:

PDF, 97 KB

english, 2002

2

Stereospecific polymerization of higher α-olefins with the solvay type catalyst TiCl3/Cp2Ti(CH3)2

Kazuo Soga, Dong Hee Lee, Takeshi Shiono, Norio Kashiwa

Journal:

Macromolecular Chemistry and Physics

Année:

1989

Langue:

english

Fichier:

PDF, 354 KB

english, 1989

3

Role of electron donor in propylene polymerization using magnesium chloride-supported titanium tetrachloride catalyst

Mamoru Kioka, Norio Kashiwa

Journal:

Journal of Molecular Catalysis

Année:

1993

Langue:

english

Fichier:

PDF, 308 KB

english, 1993

4

Study on unsaturated structures of polyhexene, poly(4-methylpentene) and poly(3-methylpentene) prepared with metallocene catalysts

Nobuo Kawahara, Junji Saito, Shingo Matsuo, Hideyuki Kaneko, Tomoaki Matsugi, Yoshihisa Toda, Norio Kashiwa

Journal:

Année:

2007

Langue:

english

Fichier:

PDF, 180 KB

english, 2007

5

The influences of cocatalyst on propylene polymerization at high temperature with a MgCl2-supported TiCl4 catalyst system

Shin-ichi Kojoh, Mamoru Kioka, Norio Kashiwa

Journal:

European Polymer Journal

Année:

1999

Langue:

english

Fichier:

PDF, 151 KB

english, 1999

6

Effect of an external donor upon chain-transfer reactions in propylene polymerization with a MgCl2-supported titanium catalyst system

Shin-ichi Kojoh, Toshiyuki Tsutsui, Norio Kashiwa, Masaaki Itoh, Akira Mizuno

Journal:

Année:

1998

Langue:

english

Fichier:

PDF, 170 KB

english, 1998

7

Establishment of De Facto Standard Catalysts in the Polypropylene Industry

Shin-ichi Kojoh, Norio Kashiwa

Journal:

The Chemical Record

Année:

2004

Langue:

english

Fichier:

PDF, 170 KB

english, 2004

8

Tacticity distribution of polypropylene prepared by MgCl2-supported titanium catalyst

Mamoru Kioka, Haruyuki Makio, Akira Mizuno, Norio Kashiwa

Journal:

Année:

1994

Langue:

english

Fichier:

PDF, 358 KB

english, 1994

9

New Titanium Complexes Having Two Pyrrolide−Imine Chelate Ligands: Syntheses, Structures, and Ethylene Polymerization Behavior

Yoshida, Yasunori, Matsui, Shigekazu, Takagi, Yukihiro, Mitani, Makoto, Nakano, Takashi, Tanaka, Hidetsugu, Kashiwa, Norio, Fujita, Terunori

Journal:

Organometallics

Année:

2001

Langue:

english

Fichier:

PDF, 95 KB

english, 2001

10

Study of the Activity Enhancement Caused by the Addition of Hydrogen in Olefin Polymerization

Kioka, Mamoru, Kashiwa, Norio

Journal:

Journal of Macromolecular Science Part A - Chemistry

Année:

1991

Langue:

english

Fichier:

PDF, 308 KB

english, 1991

11

Effect of external donor in polymerization of propylene by a MgCl2 supported titanium catalyst

Makio, Haruyuki, Kioka, Mamoru, Kashiwa, Norio

Journal:

Macromolecular Symposia

Année:

1994

Langue:

english

Fichier:

PDF, 169 KB

english, 1994

12

Syntheses, Structures and Functions of Polyolefin/non-Polyolefin Hybrids

SAITO, Junji, KAWAHARA, Nobuo, MATSUO, Shingo, KANEKO, Hideyuki, MATSUGI, Tomoaki, KASHIWA, Norio

Journal:

KOBUNSHI RONBUNSHU

Année:

2007

Fichier:

PDF, 1.33 MB

2007

13

Living Polymerization of Ethylene with a Titanium Complex Containing Two Phenoxy-Imine Chelate Ligands

Junji Saito, Makoto Mitani, Jun-ichi Mohri, Yasunori Yoshida, Shigekazu Matsui, Sei-ichi Ishii, Shin-ichi Kojoh, Norio Kashiwa, Terunori Fujita

Journal:

Angewandte Chemie

Année:

2001

Langue:

english

Fichier:

PDF, 93 KB

english, 2001

14

Living Polymerization of Ethylene with a Titanium Complex Containing Two Phenoxy-Imine Chelate Ligands

Junji Saito, Makoto Mitani, Jun-ichi Mohri, Yasunori Yoshida, Shigekazu Matsui, Sei-ichi Ishii, Shin-ichi Kojoh, Norio Kashiwa, Terunori Fujita

Journal:

Angewandte Chemie International Edition

Année:

2001

Langue:

english

Fichier:

PDF, 93 KB

english, 2001

15

Polymerization of 1-hexene with bis[N-(3-tert-butylsalicylidene)phenylaminato]titanium(IV) dichloride using iBu3Al/Ph3CB(C6F5)4 as a cocatalyst

Junji Saito, Makoto Mitani, Shigekazu Matsui, Norio Kashiwa, Terunori Fujita

Journal:

Macromolecular Rapid Communications

Année:

2000

Langue:

english

Fichier:

PDF, 70 KB

english, 2000

16

Microstructure of Highly Syndiotactic “Living” Poly(propylene)s Produced from a Titanium Complex with Chelating Fluorine-Containing Phenoxyimine Ligands (an FI Catalyst)

Junji Saito, Makoto Mitani, Mitsuhiko Onda, Jun-Ichi Mohri, Sei-Ichi Ishii, Yasunori Yoshida, Takashi Nakano, Hidetsugu Tanaka, Tomoaki Matsugi, Shin-Ichi Kojoh, Norio Kashiwa, Terunori Fujita

Journal:

Macromolecular Rapid Communications

Année:

2001

Langue:

english

Fichier:

PDF, 82 KB

english, 2001

17

A Bis(phenoxy-imine)Zr Complex for Ultrahigh-Molecular-Weight Amorphous Ethylene/Propylene Copolymer

Seiichi Ishii, Junji Saito, Sadahiko Matsuura, Yasuhiko Suzuki, Rieko Furuyama, Makoto Mitani, Takashi Nakano, Norio Kashiwa, Terunori Fujita

Journal:

Macromolecular Rapid Communications

Année:

2002

Langue:

english

Fichier:

PDF, 458 KB

english, 2002

18

A New Titanium Complex Having Two Phenoxy-Imine Chelate Ligands for Ethylene Polymerization

Junji Saito, Makoto Mitani, Shigekazu Matsui, Yasushi Tohi, Haruyuki Makio, Takashi Nakano, Hidetsugu Tanaka, Norio Kashiwa, Terunori Fujita

Journal:

Macromolecular Chemistry and Physics

Année:

2002

Langue:

english

Fichier:

PDF, 127 KB

english, 2002

19

FI Catalysts: A New Family of High Performance Catalysts for Olefin Polymerization

Haruyuki Makio, Norio Kashiwa, Terunori Fujita

Journal:

Advanced Synthesis & Catalysis

Année:

2002

Langue:

english

Fichier:

PDF, 643 KB

english, 2002

20

FI Catalysts: A New Family of High Performance Catalysts for Olefin Polymerization

Haruyuki Makio, Norio Kashiwa, Terunori Fujita

Journal:

Année:

2002

Fichier:

PDF, 25 KB

2002

21

The influence of the valence state of titanium in MgCl2-supported titanium catalysts on olefin polymerization

Norio Kashiwa, Junichi Yoshitake

Journal:

Macromolecular Chemistry and Physics

Année:

1984

Langue:

english

Fichier:

PDF, 300 KB

english, 1984

22

DSC studies of linear low density polyethylene. Insights into the disrupting effect of different comonomers and the minimum fold chain length of the polyethylene lamallae

David R. Burfield, Norio Kashiwa

Journal:

Macromolecular Chemistry and Physics

Année:

1985

Langue:

english

Fichier:

PDF, 262 KB

english, 1985

23

Characterization of isotactic polypropylene obtained with ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride as catalyst

Toshiyuki Tsutsui, Akira Mizuno, Norio Kashiwa

Journal:

Macromolecular Chemistry and Physics

Année:

1989

Langue:

english

Fichier:

PDF, 352 KB

english, 1989

24

Propylene polymerization with a high activity catalyst system: MgCl2/TiCl4—Al(C2H5)3

Norio Kashiwa, Junichi Yoshitake

Journal:

Macromolecular Rapid Communications

Année:

1983

Langue:

english

Fichier:

PDF, 179 KB

english, 1983

25

Ethylene polymerization by supported vanadium catalyst. effect of carrier on activity and relationship between concentration of v(iii) and activity

Norio Kashiwa, Toshiyuki Tsutsui

Journal:

Macromolecular Rapid Communications

Année:

1983

Langue:

english

Fichier:

PDF, 219 KB

english, 1983

26

A direct evidence for the improvement of isospecificity in Ziegler-Natta catalysts by ethyl benzoate

Kazuo Soga, Joon Ryeo Park, Takeshi Shiono, Norio Kashiwa

Journal:

Macromolecular Rapid Communications

Année:

1990

Langue:

english

Fichier:

PDF, 190 KB

english, 1990

27

Effect of hydrogen on propene polymerization with ethylenebis(1-indenyl)zirconium dichloride and methylalumoxane catalyst system

Toshiyuki Tsutsui, Norio Kashiwa, Akira Mizuno

Journal:

Macromolecular Rapid Communications

Année:

1990

Langue:

english

Fichier:

PDF, 205 KB

english, 1990

28

The microstructure of propylene homo- and copolymers obtained with a Cp2ZrCl2 and methylaluminoxane catalyst system

Toshiyuki Tsutsui, Akira Mizuno, Norio Kashiwa

Journal:

Année:

1989

Langue:

english

Fichier:

PDF, 319 KB

english, 1989

29

Propylene homo- and copolymerization with ethylene using an ethylenebis(1-indenyl) zirconium dichloride and methylaluminoxane catalyst system

Toshiyuki Tsutsui, Naoshi Ishimaru, Akira Mizuno, Akinori Toyota, Norio Kashiwa

Journal:

Année:

1989

Langue:

english

Fichier:

PDF, 569 KB

english, 1989

30

Stereostructure of regioirregular unit of polypropylene obtained with rac-ethylenebis(1-indenyl)zirconium dichloride/methylaluminoxane catalyst system studied by 13C-1H shift correlation two-dimensional nuclear magnetic resonance spectroscopy

Akira Mizuno, Toshiyuki Tsutsui, Norio Kashiwa

Journal:

Année:

1992

Langue:

english

Fichier:

PDF, 316 KB

english, 1992

31

Polymerization of propylene with an ethylene bis(1-indenyl) hafnium dichloride and methylaluminoxane catalyst system

Akinori Toyota, Toshiyuki Tsutsui, Norio Kashiwa

Journal:

Journal of Molecular Catalysis

Année:

1989

Langue:

english

Fichier:

PDF, 576 KB

english, 1989

32

Investigation of insertion reaction of 10-undecen-1-ol protected with alkylaluminum in En(Ind)2ZrCl2/MAO catalyst system

Nobuo Kawahara, Shin-ichi Kojoh, Shingo Matsuo, Hideyuki Kaneko, Tomoaki Matsugi, Norio Kashiwa

Journal:

Journal of Molecular Catalysis A: Chemical

Année:

2005

Langue:

english

Fichier:

PDF, 274 KB

english, 2005

33

Synthesis and characterization of metallocene-catalyzed propylene–ethylene copolymer with end-capped functionality

Akinori Toyota, Akira Mizuno, Toshiyuki Tsutsui, Hideyuki Kaneko, Norio Kashiwa

Journal:

Année:

2002

Langue:

english

Fichier:

PDF, 216 KB

english, 2002

34

Ethylene polymerization activity under practical conditions displayed by zirconium complexes having two phenoxy-imine chelate ligands

Naoto Matsukawa, Shigekazu Matsui, Makoto Mitani, Junji Saito, Kazutaka Tsuru, Norio Kashiwa, Terunori Fujita

Journal:

Journal of Molecular Catalysis A: Chemical

Année:

2001

Langue:

english

Fichier:

PDF, 116 KB

english, 2001

35

Highly active ethylene polymerization catalysts based on titanium complexes having two phenoxy-imine chelate ligands

Sei-ichi Ishii, Junji Saito, Makoto Mitani, Jun-ichi Mohri, Naoto Matsukawa, Yasushi Tohi, Shigekazu Matsui, Norio Kashiwa, Terunori Fujita

Journal:

Journal of Molecular Catalysis A: Chemical

Année:

2002

Langue:

english

Fichier:

PDF, 73 KB

english, 2002

36

Functionalization of polyethylene based on metallocene catalysis and its application to syntheses of new graft copolymers possessing polar polymer segments

Norio Kashiwa, Tomoaki Matsugi, Shin-Ichi Kojoh, Hideyuki Kaneko, Nobuo Kawahara, Shingo Matsuo, Tadahito Nobori, Jun-Ichi Imuta

Journal:

Journal of Polymer Science Part A: Polymer Chemistry

Année:

2003

Langue:

english

Fichier:

PDF, 277 KB

english, 2003

37

Synthesis and morphology of polyethylene-block-poly(methyl methacrylate) through the combination of metallocene catalysis with living radical polymerization

Tomoaki Matsugi, Shin-Ichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Hideyuki Kaneko, Norio Kashiwa

Journal:

Journal of Polymer Science Part A: Polymer Chemistry

Année:

2003

Langue:

english

Fichier:

PDF, 317 KB

english, 2003

38

The discovery and progress of MgCl2-supported TiCl4 catalysts

Journal:

Journal of Polymer Science Part A: Polymer Chemistry

Année:

2004

Langue:

english

Fichier:

PDF, 201 KB

english, 2004

39

Syntheses of graft and star copolymers possessing polyolefin branches by using polyolefin macromonomer

Hideyuki Kaneko, Shin-ichi Kojoh, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa

Journal:

Journal of Polymer Science Part A: Polymer Chemistry

Année:

2005

Langue:

english

Fichier:

PDF, 579 KB

english, 2005

40

Synthesis and characterization of polypropylene-based block copolymers possessing polar segments via controlled radical polymerization

Hideyuki Kaneko, Junji Saito, Nobuo Kawahara, Shingo Matsuo, Tomoaki Matsugi, Norio Kashiwa

Journal:

Journal of Polymer Science Part A: Polymer Chemistry

Année:

2009

Langue:

english

Fichier:

PDF, 281 KB

english, 2009

41

Highly active MgO-supported TiCl4catalyst for the ethylene polymerization

Norio Kashiwa, Toshiyuki Tsutsui

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 237 KB

english, 1984

42

Ethylene/propylene/5-ethylidene-2-norbornene

Norio Kashiwa, Hirokazu Kajiura, Shuji Minami

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 223 KB

english, 1984

43

Kinetic study on propylene polymerization with MgCl2/TiCl4-AlEt3/PhCO2Et System — the role of ethyl benzoate

Norio Kashiwa, Junichi Yoshitake

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 260 KB

english, 1984

44

Copolymerization of ethylene with propylene by MgCl2-containing highly active Ti catalysts

Norio Kashiwa, Akira Mizuno, Shuji Minami

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 253 KB

english, 1984

45

Solution copolymerization of ethylene with α-olefins by a MgCl2supported TiCl4catalyst

Norio Kashiwa, Toshiyuki Tsutsui, Akinori Toyota

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 252 KB

english, 1984

46

Solution copolymerization of ethylene with α-olefin by vanadium catalyst

Norio Kashiwa, Toshiyuki Tsutsui, Akinori Toyota

Journal:

Polymer Bulletin

Année:

1985

Langue:

english

Fichier:

PDF, 291 KB

english, 1985

47

Studies on propylene polymerization with a highly active MgCl2supported TiCl4catalyst system

Norio Kashiwa, Junichi Yoshitake, Akinori Toyota

Journal:

Polymer Bulletin

Année:

1988

Langue:

english

Fichier:

PDF, 310 KB

english, 1988

48

Copolymerization of propylene with a small amount of ethylene using a MgCl2/TiCl4and a TiCl3catalyst system

Norio Kashiwa, Junichi Yoshitake, Toshiyuki Tsutsui

Journal:

Polymer Bulletin

Année:

1988

Langue:

english

Fichier:

PDF, 308 KB

english, 1988

49

MgCl2supported titanium catalyst prepared by mechanical pulverization

Norio Kashiwa, Akinori Toyota

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 313 KB

english, 1984

50

Polymerizations of α-olefins and styrene with MgCl2-supported titanium catalyst system: MgCl2/TiCl4/PhCO2Et with AlEt3PhCO2Et

Norio Kashiwa, Junichi Yoshitake

Journal:

Polymer Bulletin

Année:

1984

Langue:

english

Fichier:

PDF, 201 KB

english, 1984